Nucleophilicity parameters for strong nucleophiles in dimethyl sulfoxide. A direct alternative to the s(E + N) equation
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چکیده
منابع مشابه
Nucleophilicity scale for n- and p-nucleophiles
A recently introduced empirical nucleophilicity index for a series of nand p-nucleophiles was evaluated. The index is based on the frontier molecular orbital information of the nucleophile and its electrophilic partner. The model is validated against kinetic data of alkenes, phosphanes, phosphites and amines interacting with the corresponding electrophilic partner. The predictive character of t...
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ژورنال
عنوان ژورنال: Journal of Physical Organic Chemistry
سال: 2011
ISSN: 0894-3230
DOI: 10.1002/poc.1747